Angewandte Chemie - International Edition p. 1484 - 1487 (2005)
Update date:2022-08-05
Topics:
Futatsugi, Kentaro
Yamamoto, Hisashi
Reactive, selective, and tough, the chiral Lewis acid generated from 1 and SnCl4 catalyzes the enantioselective Diels-Alder reactions of various classes of substrates (see scheme). The reactive species preserves its asymmetric induction ability even in the presence of a large excess of SnCl 4. Importantly, this catalyst system is tolerant to a small amount of moisture, oxygen, and Lewis bases.
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