ORGANOTIN-BASED BIFUNCTIONAL REAGENTS: 4-CHLORO-2-LITHIO-1-BUTENE AND RELATED SUBSTANCES. METHYLENECYCLOPENTANE ANNULATIONS. TOTAL SYNTHESIS OF (+/-)-Δ9(12)-CAPNELLENE

DOI: 10.1016/0040-4020(89)80019-5

Source and publish data:

Tetrahedron p. 1089 - 1104 (1989)

Update date:2022-08-04

Topics:

Authors:

Piers, Edward

Karunaratne, Veranja

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(89)80019-5

Transmetalation of 4-chloro-2-trimethylstannyl-1-butene (4) with MeLi in tetrahydrofuran (THF) at -78 deg C affords 4-chloro-2-lithio-1-butene (5).At low temperature (below approximately -50 to -60 deg C), 5 functions well as a bifunctional reagent.For ex

Full text of DOI:10.1016/0040-4020(89)80019-5

Products guided by the article

Product name:4-chloro-2-(1-hydroxycyclohexyl)-1-butene

Cas No:85370-37-2

R&D Labs maybe for 85370-37-2

Hangzhou Dingyan Chem Co., Ltd

website:http://www.dingyanchem.com

Contact:86-571-87157530

Address:RM.1118,NO.1 Building, Baiyun Tower,Jianggan Area, Hangzhou city, China,310004
Tianjin Anda North Industrial & Business Co.Ltd.

Contact:86-22-24999306

Address:No.11 Erwei Road,Dongli Development Area,Tianjin,China
NEW FORTUNE INDUSTRIAL CO.,LTD.

website:http://newfortune.lookchem.com/

Contact:+86-25-8645-9456

Address:C4-105 GREEN ISLAND FLOWER TOWN
Liaoning Yufeng Chemical Co.,Ltd.

Contact:86-0419-3418888

Address:The metallurgical industrial zone,shoushan town, Liaoyang, Liaoning, China
Du-Hope International Group

website:http://www.np-chem.com

Contact:0086-25-52346877

Address:199, Jian Ye Road, Nanjing, China

Relevant to this article

Doi:10.1021/ja01609a050
(1955)
Total Asymmetric Synthesis of (+)-Paroxetine and (+)-Femoxetine

Doi:10.1002/ejoc.201901389
(2019)
Doi:10.1021/ja01238a008
(1944)
Doi:10.1111/j.1751-0813.2001.tb10671.x
(1937)
Efficient solution phase synthesis of 2-(N-acyl)-aminobenzimidazoles

Doi:10.1016/S0040-4039(02)01754-9
(2002)
Doi:10.1021/jo01152a015
(1950)

Article Doi