
Journal of the Chemical Society. Chemical communications p. 1419 - 1420 (1995)
Update date:2022-08-03
Topics:
Besson, Thierry
Emayan, Kumaraswamy
Rees, Charles W.
Anthranilic acid and 4,5-dichloro-1,2,3-dithiazolium chloride 1 give the delicate dithiazoloimino carboxylic acid 8 which on mild thermolysis gives 2-cyano-3,1-benzoxazin-4-one 6 and with triphenylphosphine gives 2-cyano-3,1-benzothiazin-4-one 7, both quantitatively; in general N-aryliminodithiazoles 2 with triphenylphosphine give the corresponding cyanothioformanilides 3, providing a route to these compounds from anilines in two mild steps.
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