Journal of the American Chemical Society p. 3893 - 3898 (1983)
Update date:2022-09-26
Topics:
Faller
Chao
Nucleophilic attack on mixtures of endo and exo isomers of molybdenum complexes provide facile routes to optically pure allylically substituted olefins. A given configuration at the metal center controls the configuration at the allylic center because the exo isomer is attacked preferentially and attack occurs cis to the nitrosyl. Full-matrix least-squares refinement using anisotropic thermal parameters for the molybdenum and isotropic thermal parameters for the remaining non-hydrogen atoms converged to the final residuals R//1 equals 0. 069 and R//2 equals 0. 066.
View Moresuzhou chukai pharmateach co,.ltd
Contact:86-512-88812511
Address:Building 3, Wujiang Scientific Innovation Park, 2358 Changan Rd, Wujiang 215200, Jiangsu Province, P. R. China
Contact:+86 512 6287 2180
Address:398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu, P. R. China
Contact:86-516-66656369
Address:The west road of Huaihai, Xuzhou, China
Contact:+86-18653358619
Address:zibo
Contact:86-574-83851061 86-574-87083208
Address:Room 905, No.3 Building,East Business Center, 456 Xingning Road, Ningbo City,China
Doi:10.1080/00397910802632589
(2009)Doi:10.1016/S0020-1693(00)84616-2
(1986)Doi:10.1021/ja01257a003
(1942)Doi:10.1021/ja01171a022
(1949)Doi:10.1002/anie.200462141
(2005)Doi:10.1002/ejoc.201800861
(2018)