Tetrahedron Letters p. 5021 - 5024 (1982)
Update date:2022-08-04
Topics:
Stamm, H.
Assithianakis, P.
Buchholz, B.
Weiss, R.
Regioselectivity of nucleophilic attack on 2,2-dimethylaziridines depends on the degree of leaving group activation: in highly activated aziridines it occures at the methylene carbon and in less activated at the tertiary carbon.This latter abnormal ring opening is explained by an SET mechanism.
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Doi:10.1016/0008-6215(83)88201-9
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