PHOTOCATALYTIC FORMATION OF SCHIFF BASES FROM PRIMARY AMINES BY PLATINIZED-TiO2 SUSPENSION IN ACETONITRILE

DOI: 10.1246/cl.1985.1075

Source and publish data:

Chemistry Letters p. 1075 - 1078 (1985)

Update date:2022-08-05

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Authors:

Ohtani, Bunsho

Osaki, Haruyoshi

Nishimoto, Sei-Ichi

Kagiya, Tsutomu

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Article abstract of DOI:10.1246/cl.1985.1075

Photoirradiation (λ_ex>300nm) of platinized TiO2 suspended in Ar-purged acetonitrile solution of aliphatic and aromatic primary amines produced Schiff bases together with H2 and NH3 at room temperature.Solvent acetonitrile was partly reduced on the Pt site to inhibit the reduction of the Schiff bases into secondary amines.

Full text of DOI:10.1246/cl.1985.1075

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