Chemistry Letters p. 1075 - 1078 (1985)
Update date:2022-08-05
Topics:
Ohtani, Bunsho
Osaki, Haruyoshi
Nishimoto, Sei-Ichi
Kagiya, Tsutomu
Photoirradiation (λex>300nm) of platinized TiO2 suspended in Ar-purged acetonitrile solution of aliphatic and aromatic primary amines produced Schiff bases together with H2 and NH3 at room temperature.Solvent acetonitrile was partly reduced on the Pt site to inhibit the reduction of the Schiff bases into secondary amines.
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