Borane/Bu2BOTf: A mild reagent for the regioselective reductive ring opening of benzylidene acetals in carbohydrates

DOI: 10.1016/S0040-4039(97)10599-8

Source and publish data:

Tetrahedron Letters p. 355 - 358 (1998)

Update date:2022-08-03

Topics:

Authors:

Jiang, Lu

Chan, Tak-Hang

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)10599-8

BH₃/Bu₂OTf is an effective reagent to reductively cleave 4,6-O-benzylidene acetals of various hexopyranosides to the corresponding 4-O-benzyl ethers. 4,6-O-Isopropylidene acetals can be similarly cleaved. Common protecting groups are

Full text of DOI:10.1016/S0040-4039(97)10599-8

Products guided by the article

Product name:(2S,3R,4R,5S,6R)-4,5-Bis-benzyloxy-6-hydroxymethyl-2-methoxy-tetrahydro-pyran-3-ol

Cas No:86172-90-9

R&D Labs maybe for 86172-90-9

BAODING SINO-CHEM INDUSTRY CO.,LTD

Contact:0312-5956088

Address:NO.8 FUXING ROAD,CHINA
Zhejiang Kente Chemical Co.,Ltd.

Contact:86-0576-87651912

Address:No.7, Fengxi West Road, Modern Industrial Zone
Zhejiang Chemline International Co., Ltd.

Contact:+86-571-88062298

Address:Hengdian Industry Area, Dongyang, Zhejiang, China
Changzhou Foreign Trade Corp

Contact:+86-519-86623222

Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China
BrightGene Bio-Medical Technology Co., Ltd.

website:https://en.bright-gene.com/

Contact:+86-512-62551801

Address:Building C25 - C31, No. 218 Xinghu Road, Suzhou Industrial Park, Suzhou, Jiangsu, China.

Relevant to this article

4,5-Didehydro-7-silyloxymethyl-2-oxepanone and formal total syntheses of Hagen's gland lactones and trans-kumausynes

Doi:10.1016/j.tetlet.2006.08.059
(2006)
A simplified synthesis of 8-substituted purine nucleosides via lithiation of 6-chloro-9-(2,3-O-isopropylidene-β-D-ribofuranosyl)purine

Doi:10.1248/cpb.31.787
(1983)
Catalytic ester-amide exchange using group (IV) metal alkoxide-activator complexes

Doi:10.1021/ja0527976
(2005)
FACILE REDUCTION OF CARBON DIOXIDE, CARBONYL SULFIDE, AND CARBON DISULFIDE BY COPPER(I) BOROHYDRIDE. X-RAY CRYSTAL STRUCTURE OF THE COMPLEX <(triphos)Cu(O2CH)>

Doi:10.1016/0022-328X(83)85031-1
(1983)
Well-defined iron catalysts for the acceptorless reversible dehydrogenation-hydrogenation of alcohols and ketones

Doi:10.1021/cs5009656
(2014)
Convenient phosphorus tribromide induced syntheses of substituted 1-arylmethylnaphthalenes from 1-tetralone derivatives

Doi:10.1016/j.tetlet.2005.06.016
(2005)

Article Doi