FACILE REDUCTION OF CARBON DIOXIDE, CARBONYL SULFIDE, AND CARBON DISULFIDE BY COPPER(I) BOROHYDRIDE. X-RAY CRYSTAL STRUCTURE OF THE COMPLEX

DOI: 10.1016/0022-328X(83)85031-1

Source and publish data:

Journal of Organometallic Chemistry p. C13 - C16 (1983)

Update date:2022-08-03

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Authors:

Bianchini,Claudio

Ghilardi, Carlo A.

Meli, Andrea

Midollini, Stefano

Orlandini, Annabella

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Article abstract of DOI:10.1016/0022-328X(83)85031-1

The copper(I)-borohydride complex <(triphos)Cu(BH4)> reacts with CO2, CS2, and COS under very mild conditions to give formate, dithioformate, or thioformate copper(I) complexes, respectively.A complete X-ray structure determination has been carried out on the formate complex <(triphos)Cu(O2CH)>.

Full text of DOI:10.1016/0022-328X(83)85031-1

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