ETUDE DE L'ADDITION NUCLEOPHILE DE QUELQUES THIOLS SUR LES ALCYN-1 OLS-3; ADDITIONS REGIO- ET STEREO-SELECTIVES DU METHYL-2 PROPANETHIOL-2.

DOI: 10.1016/S0040-4039(00)81327-1

Source and publish data:

Tetrahedron Letters p. 61 - 64 (1983)

Update date:2022-07-29

Topics:

Authors:

Ruel, Odile

Guittet, Eric

Julia, Sylvestre

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Article abstract of DOI:10.1016/S0040-4039(00)81327-1

The >=92percent regioselective nucleophilic trans-addition of 2-methyl-2-propanethiol to primary, secondary and tertiary 1-alkyn-3-ols, catalyzed by 0.1 equiv. of potassium hydroxide powder, affords good yields of anti- Markovnikoff products.

Full text of DOI:10.1016/S0040-4039(00)81327-1

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