Tetrahedron Letters p. 61 - 64 (1983)
Update date:2022-07-29
Topics:
Ruel, Odile
Guittet, Eric
Julia, Sylvestre
The >=92percent regioselective nucleophilic trans-addition of 2-methyl-2-propanethiol to primary, secondary and tertiary 1-alkyn-3-ols, catalyzed by 0.1 equiv. of potassium hydroxide powder, affords good yields of anti- Markovnikoff products.
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