Reaction Mechanism of 2-(Trimethylsilyl)pyridine with Benzonitrile

DOI: 10.1246/bcsj.56.1241

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1241 - 1242 (1983)

Update date:2022-08-03

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Authors:

Konakahara, Takeo

Sato, Kenji

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Article abstract of DOI:10.1246/bcsj.56.1241

The mechanism of the reaction of lithiated 2-(trimethylsilylmethyl)pyridine with benzonitrile is discussed.The reaction proceeds through (E) and (Z)-1-phenyl-2-(2-pyridyl)-1-(trimethylsilylamino)ethene, which are quantitatively converted to 2-phenacylpyridine by acidic hydrolysis.

Full text of DOI:10.1246/bcsj.56.1241

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