Reaction Mechanism of 2-(Trimethylsilyl)pyridine with Benzonitrile

DOI: 10.1246/bcsj.56.1241

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1241 - 1242 (1983)

Update date:2022-08-03

Topics:

Authors:

Konakahara, Takeo

Sato, Kenji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.56.1241

The mechanism of the reaction of lithiated 2-(trimethylsilylmethyl)pyridine with benzonitrile is discussed.The reaction proceeds through (E) and (Z)-1-phenyl-2-(2-pyridyl)-1-(trimethylsilylamino)ethene, which are quantitatively converted to 2-phenacylpyridine by acidic hydrolysis.

Full text of DOI:10.1246/bcsj.56.1241

Products guided by the article

Product name:(E)-1-phenyl-2-(2-pyridyl)-1-(trimethylsilylamino)ethene

Cas No:86370-66-3

R&D Labs maybe for 86370-66-3

henan victory industry co.ltd

Contact:86-371-63655023

Address:No.85,jinshui road,zhengzhou,China
SHAANXI FUJIE PHARMACEUTICAL CO.,LTD

website:http://www.fujiepharm.com

Contact:+86-29-63650906

Address:Yuanqu Yi Road, Qinghe Food Industrial Park, Sanyuan County, Shaanxi Province, China
Shanghai Mio Chemical Co., Ltd

Contact:0086 21- 64401188-622

Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China
Changzhou Welton Chemical Co., Ltd,

Contact:0086-519-85910828,85920537,85912897

Address:No.8 Jinlong Road, Binjiang Park, Changzhou, Jiangsu, China.
Qingdao Kingway Pharmtech Co., Ltd.

Contact:86-532-87118899

Address:No. 88, Middle Haixi Road, Jiaonan City, Qingdao, China

Relevant to this article

REACTIVE ORGANOMETALLIC COMPOUNDS FROM METALLOCENES.

Doi:10.1351/pac198456010063
(1983)
Synthesis of the tetrahydroisoquinoline alkaloid (±)-renieramycin G and a (zb)-lemonomycinone analogue from a common intermediate

Doi:10.1021/ja0535817
(2005)
Enantioselective Allylation of Alkenyl Boronates Promotes a 1,2-Metalate Rearrangement with 1,3-Diastereocontrol

Doi:10.1021/jacs.1c01242
(2021)
Deoxynucleoside Triphosphate Containing Pyridazin-3-one Aglycon as a Thymidine Triphosphate Substitute for Primer Extension and Chain Elongation by Klenow Fragments

Doi:10.1021/acs.joc.8b00918
(2018)
Exciton chirality. (A) origins of and (B) applications from strongly fluorescent dipyrrinone chromophores

Doi:10.1007/s00706-004-0278-3
(2005)
Synthesis and antitumor activity of new amphiphilic alkylglycerolipids substituted with a polar head group, 2-(2-trimethylammonioethoxy)ethyl or a congeneric oligo(ethyleneoxy)ethyl group

Doi:10.1248/cpb.37.3277
(1989)

Article Doi