
Bulletin of the Chemical Society of Japan p. 1241 - 1242 (1983)
Update date:2022-08-03
Topics:
Konakahara, Takeo
Sato, Kenji
The mechanism of the reaction of lithiated 2-(trimethylsilylmethyl)pyridine with benzonitrile is discussed.The reaction proceeds through (E) and (Z)-1-phenyl-2-(2-pyridyl)-1-(trimethylsilylamino)ethene, which are quantitatively converted to 2-phenacylpyridine by acidic hydrolysis.
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Doi:10.1351/pac198456010063
(1983)Doi:10.1021/ja0535817
(2005)Doi:10.1021/jacs.1c01242
(2021)Doi:10.1021/acs.joc.8b00918
(2018)Doi:10.1007/s00706-004-0278-3
(2005)Doi:10.1248/cpb.37.3277
(1989)