Pure and Applied Chemistry p. 63 - 80 (1983)
Update date:2022-08-03
Topics:
Jonas
Metallocenes can be converted into reactive organometallic compounds having readily accessible coordination sites by removing one or both of the C//5H//5-ligands: two types of reaction are discussed by which this can be achieved. Aspects to be covered include the synthesis of (C//5H//5)Co(C//2H//4)//2 and its application as a catalyst precursor for the cobalt-catalyzed alkyne cyclooligomerization and the cotrimerization of alkynes and nitriles. Also reported are the alkali metal cobaltates M//A left bracket Co(C//2H//4)//4 right bracket and M//A left bracket Co(cod)//2 right bracket (M//A equals alkali metal) which can be used as starting materials for the preparation of new catalysts for the hydrogenation of olefins and arenes. Finally, a series of novel binuclear complexes of Co, Fe and V is presented that are the first examples in which eta **6 -arene ligands are bonded to two metal centers.
Contact:18710867521(wechat)
Address:Rm10516,Galaxy Tech Building #2,No.25 Tangyan Rd,Hi-Tech Zone,Xi'an, China
Jinan Boss Chemical Industry Co., Ltd.【revoke the business license】
website:http://www.chemboss.com.cn
Contact:+86-531-58591595
Address:No2.Hualong Road, Jinan, China
Suzhou SuKaiLu Chemical Technology Co., Ltd.
Contact:+86-512-62766020
Address:Floor 4, Building 1, Xinyi Pharmaceutical Valley Wisdom Industrial Park, 415 Changyang Street, Suzhou Industrial Park, Jiangsu Province
Contact:+86-371-67759225
Address:No.32, Jinsuo Road, High-tech Zone
Nanjing Spring & Autumn Biological Engineering Co., Ltd.
Contact:86-180510-83338
Address:Suite# 210, No. 1 BuildingNanjing Agricultural Biotechnology High-tech Entrepreneurship Center, No. 4 Tongwei Road, Xuanwu District, Nanjing,China
Doi:10.1039/c7ra12977g
(2018)Doi:10.1002/hlca.19860690227
(1986)Doi:10.1271/bbb.69.113
(2005)Doi:10.1002/adsc.201901560
(2020)Doi:10.1002/ejoc.200500053
(2005)Doi:10.1081/CAR-200067114
(2005)
