REMOTE SUBSTITUENT EFFECT ON THE REGIOSELECTIVITY IN THE BAEYER-VILLIGER OXIDATION OF 5α-CHOLESTAN-6-ONE DERIVATIVES

DOI: 10.1016/S0040-4039(00)81564-6

Source and publish data:

Tetrahedron Letters p. 917 - 920 (1983)

Update date:2022-08-05

Topics:

Authors:

Takatsuto, Suguru

Ikekawa, Nobuo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)81564-6

The regioselectivity in the Baeyer-Villiger oxidation of 5α-cholestan-6-one derivatives was markedly affected by the substituents at C-1, 2 or 3 position which were located at γ or δ position from the reaction center C-6.

Full text of DOI:10.1016/S0040-4039(00)81564-6

Products guided by the article

Product name:Toluene-4-sulfonic acid (1R,3aS,3bS,6aS,9S,10aR,10bS,12aR)-1-((R)-1,5-dimethyl-hexyl)-10a,12a-dimethyl-6-oxo-hexadecahydro-5-oxa-benzo[3,4]cyclohepta[1,2-e]inden-9-yl ester

Cas No:86401-38-9

R&D Labs maybe for 86401-38-9

Wuhan Kemi-Works Chemical Co., Ltd

website:http://www.kemiworks.com

Contact:86-27-85736489

Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China
Suzhou Howsine Biological Technology Co.,Ltd(expird)

website:http://www.howsine.com

Contact:86-512-67262751

Address:No 3,Weihua Road ,Suzhou Industrial Park ,Jiangsu ,China.
Kono Chem Co.,Ltd

website:http://www.konochem.com

Contact:86-29-86107037-8015

Address:No.11 Daqing Road,Lianhu District,Xi’an 710082,China
Kaiping Genuine Biochemical Pharmaceutical Co.,Ltd.

Contact:+86-750-2881198

Address:No.1, Xinke Road, Shatang Town, Kaiping, Guangdong Province, P.R.China
Xian Changyue Biological Technology Co., Ltd.

website:https://www.xachangyue.com/

Contact:+86-029-62886900

Address:Keji Road NO.70

Relevant to this article

Doi:10.1039/jr9470000618
(1947)
Glycosides of hydroxylamine derivatives: I. Phase transfer synthesis and the study of the influence of glucosaminides of isatine 3-oximes on bacterial luminescence

Doi:10.1134/S1068162011020105
(2011)
Reactions of cyclopentadienyl-amidinate titanium hydrazides with CO ₂, CS₂, and isocyanates: Ti=N_α cycloaddition, cycloaddition-insertion, and cycloaddition-NNR₂ group transfer reactions

Doi:10.1021/om101167p
(2011)
Preparation of 2-azido-1-substituted-1 H-benzo[d]imidazoles using a copper-promoted three-component reaction and their further conversion into 2-amino and 2-triazolyl derivatives

Doi:10.1002/chem.201202215
(2012)
Further Studies of Selenosulfonation. Photoaddition of Bis(p-tolylsulfonyl)Selenide and Alkaneselenosulfonates to Alkenes and the Selenosulfonation of β-Pinene and 1,6-Heptadiene

Doi:10.1021/jo00183a006
(1984)
Synthesis of 5-(arylamino)-1-benzyluracils

Doi:10.1007/s10593-005-0218-0
(2005)

Article Doi