ALTERNATIV-LIGANDEN XVI. KOMPLEXE M(CO)nL (M = Cr, Mo, W) DER CHELATLIGANDEN (2-Me2E'C6H4)Si(EMe2)Me2 UND (4-XC6H4)SiMe(EMe2)CH2CH2E'Me2 (Me=CH3; X=F, Cl; E, E'=N, P, As)

DOI: 10.1016/S0022-328X(00)98803-X

Source and publish data:

Journal of Organometallic Chemistry p. 103 - 126 (1983)

Update date:2022-07-29

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Authors:

Aslanidis, P.

Grobe, J.

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Article abstract of DOI:10.1016/S0022-328X(00)98803-X

Reactions of M(CO)4NBD (NBD=norbornadiene; M=Cr, Mo, W) with (2-Me2E'C6H4)Si(EMe2 ligands (E'=P, As; E=N, P, As) afford the chelate complexes M(CO)4(2-Me2E'C6H4)Si(EMe2)Me2 in yields of 30-80percent.However, under similar conditions (2-Me2NC6H4)Si(PMe2)Me

Full text of DOI:10.1016/S0022-328X(00)98803-X

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Product name:Mo(CO)4[((CH₃)2NC₆H₄)Si(P(CH₃)2)(CH₃)2]2

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