THE PHOTOCHEMICAL REARRANGEMENT OF 3-AZA-1,2,2,4,4-PENTAPHENYLBUT-3-EN-1-ONE. A NOVEL REACTION IN A β,γ-UNSATURATED ENONE.

DOI: 10.1016/S0040-4039(00)81612-3

Source and publish data:

Tetrahedron Letters p. 1089 - 1092 (1983)

Update date:2022-07-29

Topics:

Authors:

Armesto, Diego

Gallego, Mar G.

Perez-Ossorio, Rafael

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Article abstract of DOI:10.1016/S0040-4039(00)81612-3

Irradiation of 3-aza-1,2,2,4,4-pentaphenylbut-3-en-1-one in t-butanol gives two photoproducts in good yield.The formation of these products is interpreted in terms of 1,3- or 1,5-benzoyl migration.This is the first report of an acyl migration from a saturated carbon into a substituent phenyl group.

Full text of DOI:10.1016/S0040-4039(00)81612-3

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