Diastereodivergent Control in the Reactions of Allylic and Allenic Organometallic Reagents with Pyruvates

DOI: 10.1021/jo00356a026

Source and publish data:

Journal of Organic Chemistry p. 886 - 891 (1986)

Update date:2022-08-03

Topics:

Authors:

Yamamoto, Yoshinori

Maruyama, Kazuhiro

Komatsu, Toshiaki

Ito, Wataru

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00356a026

The reaction of crotyl-9-BBN (4a) with pyruvates (3) produced the threo (anti) isomer 5 either predominantly or exclusively.On the other hand, the reaction of allenic organometallic reagents 18 (M = B or Ti) gave the erythro (syn) isomer 20 preferentially

Full text of DOI:10.1021/jo00356a026

Products guided by the article

Product name:2,6-di-tert-butyl-4-methylphenyl threo-2,3-dimethyl-2-hydroxy-4-pentenoate

Cas No:86577-52-8

R&D Labs maybe for 86577-52-8

SHANDONG ZHANHUA YONGHAO PHARMACEUTICAL TECH.CO.,LTD

Contact:+86-576-88685096

Address:GENGJU VILLAGE NORTH ONE KILOMETER,ZHANHUA DISTRICT,BINZHOU CITY,SHANDONG PROVINCE,CHINA.
Mollt Biochem Co., Ltd(expird)

Contact:+86-21-38682181

Address:shanghai ,china
YORK CHEMICALS LTD

Contact:+1 (647) 918 5848

Address:2343 BRIMLEY RD., Suite 250
Chongqing Shuangfeng Chemical Co.,Ltd

Contact:+86-23-49850156

Address:No.663,xuanhua Rd,yongchuan,chongqing,China
Joyochem Co., Ltd.

website:https://sdjingyuan.lookchem.com/

Contact:86-531-82687998

Address:Factory Building 11, Jinan Comprehensive free trade zone, Shandong, China

Relevant to this article

Efficient total synthesis of iso-cladospolide B and cladospolide B

Doi:10.1016/j.tetlet.2005.07.153
(2005)
Synthesis of 2,3-dialkylindoles from 2-alkenylphenylisocyanides and imines by silyltelluride- and tin hydride-mediated sequential radical reactions

Doi:10.1055/s-2005-871931
(2005)
Investigation of functionally liver selective glucokinase activators for the treatment of type 2 diabetes

Doi:10.1021/jm900839k
(2009)
Syntheses of fluorinated ligands to probe binding of antigenic determinants of Vibrio cholerae O:1, serotypes Inaba and Ogawa, to antibodies

Doi:10.1016/S0957-4166(99)00505-4
(2000)
Doi:10.1002/ardp.19512840407
(1951)
Convenient enantiopure synthesis of (2S,3R)-2-O-benzyl-3,4-O- isopropylidene-D-erythritol from D-(+)-glucono-δ-lactone: A potential C₄ chiral building block

Doi:10.1055/s-2005-869986
(2005)

Article Doi