Diastereodivergent Control in the Reactions of Allylic and Allenic Organometallic Reagents with Pyruvates

DOI: 10.1021/jo00356a026

Source and publish data:

Journal of Organic Chemistry p. 886 - 891 (1986)

Update date:2022-08-03

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Authors:

Yamamoto, Yoshinori

Maruyama, Kazuhiro

Komatsu, Toshiaki

Ito, Wataru

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Article abstract of DOI:10.1021/jo00356a026

The reaction of crotyl-9-BBN (4a) with pyruvates (3) produced the threo (anti) isomer 5 either predominantly or exclusively.On the other hand, the reaction of allenic organometallic reagents 18 (M = B or Ti) gave the erythro (syn) isomer 20 preferentially

Full text of DOI:10.1021/jo00356a026

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