STUDIES ON THE EFFECT OF REMOTE SUBSTITUENTS ON STEREOREACTIVITY. III. INFLUENCE OF DIRECT ELECTRONIC ACTIVATION OF THE DIPOLAROPHILIC DOUBLE-BOND ON THE COURSE OF DIAZOALKANES CYCLOADDITION TO 7 - HALONORBORNADIENES

DOI: 10.1016/S0040-4039(00)81664-0

Source and publish data:

Tetrahedron Letters p. 1391 - 1394 (1983)

Update date:2022-08-05

Topics:

Authors:

Franck-Neumann, M.

Sedrati, M.

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Article abstract of DOI:10.1016/S0040-4039(00)81664-0

The remarkable endo-anti stereospecifity of diazoalkane cycloadditions to 7-halogenated norbornadienes remains almost unaltered when the reactivity of the anti double bond is strongly enhanced by carbomethoxy substituents.

Full text of DOI:10.1016/S0040-4039(00)81664-0

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