A HORNER-WITTIG SOLUTION TO THE SYNTHESIS OF KETENE O,O-ACETALS

DOI: 10.1016/S0040-4039(00)81641-X

Source and publish data:

Tetrahedron Letters p. 1303 - 1306 (1983)

Update date:2022-08-05

Topics: Synthesis Yield Nucleophile Electrophile Solvent Alkene Anhydrous conditions Purification Reaction Mechanism Spectroscopic Analysis Stoichiometry carbonyl compound Horner-Wittig reaction Phosphonate ester

Authors:

Schaik, T. A. M. van

Henzen, A. V.

Gen, A. van der

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Article abstract of DOI:10.1016/S0040-4039(00)81641-X

Aldehydes as well as ketones can be converted into their homologous ketene O,O-acetals by a Horner-Wittig reaction with dialkoxymethyl diphenylphosphine oxides.

Full text of DOI:10.1016/S0040-4039(00)81641-X

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Product name:Cyclohexanol, 1-[(diphenylphosphinyl)diethoxymethyl]-

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