Bulletin of the Chemical Society of Japan p. 1555 - 1556 (1983)
Update date:2022-08-05
Topics:
Isogai
Nishizawa
Saito
Sakai
The title compounds were hydrogenolyzed over PdO or Raney nickel. The C//2-C//3 bond of the cyclopropane ring underwent cleavage exclusively over both catalyts. The contribution of the fluorine substituent to the lengthening and weakening the C//2-C//3 bond of the cyclopropane ring seems to become a dominant factor in regioselectivity.
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