Enantioselective ring construction: Synthesis of (+)-estrone methyl ether

DOI: 10.1021/jo00377a005

Source and publish data:

Journal of Organic Chemistry p. 28 - 34 (1987)

Update date:2022-08-05

Topics: Synthesis Enantioselective Ring Construction

Authors:

Taber, Douglass F.

Raman, Krishna

Gaul, Micheal D.

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Article abstract of DOI:10.1021/jo00377a005

A general method for the construction of functionalized cyclopentane derivatives 10 of high optical purity, via diastereoselective intramolecular C-H insertion, is described. A methylation-retro Dieckmann dianion alkylation procedure on 10b (R = vinyl) gi

Full text of DOI:10.1021/jo00377a005

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