Bulletin of the Chemical Society of Japan p. 3607 - 3612 (1988)
Update date:2022-08-05
Topics:
Kanemoto, Shigekazu
Matsubara, Seijiro
Takai, Kazuhiko
Oshimara, Koichiro
Utimoto, Kiitiro
Nozaki, Hitosi
Bis(trimethylsilyl) peroxide (BTSP) serves as an effective oxidant of alcohols in the presence of chromium(VI) or ruthenium(II) complexes as catalysts in dichloromethane.Selective oxidation of primary alcohols in preference to secondary ones using RuCl2(PPh3)3 as a catalyst is also described.
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