Chromium(VI) or Ruthenium(II) Complex Catalysis in Oxidation of Alcohols to Aldehydes and Ketones by Means of Bis(trimethylsilyl) Peroxide

DOI: 10.1246/bcsj.61.3607

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3607 - 3612 (1988)

Update date:2022-08-05

Topics:

Authors:

Kanemoto, Shigekazu

Matsubara, Seijiro

Takai, Kazuhiko

Oshimara, Koichiro

Utimoto, Kiitiro

Nozaki, Hitosi

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Article abstract of DOI:10.1246/bcsj.61.3607

Bis(trimethylsilyl) peroxide (BTSP) serves as an effective oxidant of alcohols in the presence of chromium(VI) or ruthenium(II) complexes as catalysts in dichloromethane.Selective oxidation of primary alcohols in preference to secondary ones using RuCl2(PPh3)3 as a catalyst is also described.

Full text of DOI:10.1246/bcsj.61.3607

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