Tetrahedron Letters p. 1651 - 1654 (1985)
Update date:2022-08-05
Topics:
Tomioka, Hideo
Hayashi, Norihiro
Inoue, Noboru
Izawa, Yasuji
Aryloxymethylchlorocarbene generated by photolysis of the corresponding diazirine afforded α-aryloxy-β-chloroalkene.The thermodynamically less stable Z-products are the major isomers and its content becomes dominant as more electron-withdrawing groups are
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