Site of Attack of a Carbene on Alkylbenzenes, Naphthalene, and Thiophene and the Norcaradiene-Cycloheptatriene Equilibration

DOI: 10.1021/jo00170a025

Source and publish data:

Journal of Organic Chemistry p. 4002 - 4010 (1983)

Update date:2022-08-05

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Authors:

Bedford, Clifford D.

Smith, Peter A. S.

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Article abstract of DOI:10.1021/jo00170a025

Upon thermolysis at 40-50 degC, 5-(diazomethyl)-1,4-diphenyl-1,2,3-triazole (1) reacts with p-ethyltoluene, p-cymene, p-tert-butyltoluene, p-diisopropylbenzene, durene, and naphthalene to give a mixture of carbene-derived cycloheptatriene/norcaradiene pro

Full text of DOI:10.1021/jo00170a025

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Product name:1-Methyl-4-isopropyl-7-(1,4-diphenyl-1,2,3-triazol-5-yl)cycloheptatriene

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