A NEW APPROACH TO GEPHYROTOXIN

DOI: 10.1016/S0040-4039(00)88049-1

Source and publish data:

Tetrahedron Letters p. 2881 - 2884 (1983)

Update date:2022-07-31

Topics:

Authors:

Ito, Y. Ito, Y.

Nakajo, E.

Nakatsuka, M.

Saegusa, T.

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Article abstract of DOI:10.1016/S0040-4039(00)88049-1

CsF induced 1,4-elimination of ammonium bromide 1a and the subsequent intramolecular cyclization of the resulting o-quinone methide N-alkenylimine 2a afforded benzoindolizidine 4a as a 4 ca. 5 : 1 stereoisomeric mixture.Hydrogenation of 4a with 5percen

Full text of DOI:10.1016/S0040-4039(00)88049-1

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Product name:[2-Methoxy-6-({1-[2-(tetrahydro-pyran-2-yloxy)-ethyl]-pent-4-enyl}-trimethylsilanyl-amino)-benzyl]-trimethyl-ammonium; bromide

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