Oxidation of a Diphosphene and Dechlorination of an Arylphosphonic Dichloride: Isolation of the Diphosphene Oxide

DOI: 10.1039/c39830000419

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 419 - 420 (1983)

Update date:2022-08-05

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Authors:

Yoshifuji, Masaaki

Ando, Kaori

Toyota, Kozo

Shima, Ichiro

Inamoto, Naoki

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Article abstract of DOI:10.1039/c39830000419

The dechlorination reaction of the phosphonic dichloride ArP(O)Cl2 (Ar = 2,4,6-Bu^t3C6H2) with magnesium gave the sterically protected diphosphene oxide ArP(O)=PAr as a stable compound.

Full text of DOI:10.1039/c39830000419

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