Chemistry Letters p. 985 - 988 (1983)
Update date:2022-08-05
Topics:
Mukaiyama, Teruaki
Oriyama, Takeshi
Murakami, Masahiro
Cyanohydrin silyl ethers, prepared by trimethylsilylcyanation of glyoxylic esters, smoothly react with LDA (lithium diisopropylamide) to yield the lithium salts, which in turn react with alkyl halides such as allyl bromide to give, after acetylation, the corresponding enol acetates of α-keto esters in good yields.
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Doi:10.1002/chem.201503359
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(2000)Doi:10.1016/S0040-4020(02)00700-7
(2002)Doi:10.1246/bcsj.71.2673
(1998)Doi:10.1135/cccc19981549
(1998)Doi:10.1016/S0960-894X(98)00529-0
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