Journal of Organic Chemistry p. 4701 - 4705 (1983)
Update date:2022-09-26
Topics:
Israel, Robert J.
Murray, Roger K.
Oxidation of homoadamantane with chromic acid, lead tetraacetate, p-nitroperbenzoic acid, or bromine occurs by competitive attack at the C-3 (major) and C-1 (minor) bridgehead positions.In striking contrast, dry ozonation of homoadamantane adsorbed on silica gel leads to regiospecific substitution at the chemically equivalent C-3 and C-6 bridgehead positions.A consequence of this observation is that some 1,3- and 3,6-disubstituted homoadamantanes can be prepared by dry ozonation of suitably substituted homoadamantane derivatives.
View MoreSHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD
Contact:86-21-60560171
Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China
Contact:+86-571-86025531 / 86024803
Address:1218-24 Guangyin Mansion,42 Fengqi East Road
Shandong Jiulong Hisince Pharmaceutical Co.,Ltd.
Contact:+86-15853188990
Address:Huadian Pioneer Park, Huadian Township, Qihe County, Dezhou City, Shandong, P.R.China
Hangzhou Deli Chemical Co.,Ltd.
website:http://www.dlchemical.com
Contact:86 571 28006267
Address:Tangxi Industrial Area, Yuhang District, Hangzhou
Taixing Joxin Bio-tec Co.,Ltd.
website:http://www.joxbio.com
Contact:86-523-87558858 87612088
Address:No.88, chengdong industrial park
Doi:10.1016/j.tetlet.2014.08.096
(2014)Doi:10.1016/j.tetlet.2018.10.068
(2018)Doi:10.1016/j.ica.2005.06.009
(2006)Doi:10.1055/s-2005-924765
(2006)Doi:10.1016/0008-6215(83)88415-8
(1983)Doi:10.1002/chem.201605648
(2017)