A SILYL-FUNCTIONALIZED ALKYL AZIDE, TRIMETHYLSILYLMETHYL AZIDE; SYNTHESIS AND CYCLOADDITION REACTION TO ACETYLENIC DIPOLAROPHILES

DOI: 10.1246/cl.1983.1131

Source and publish data:

Chemistry Letters p. 1131 - 1134 (1983)

Update date:2022-08-05

Topics:

Authors:

Tsuge, Otohiko

Kanemasa, Shuji

Matsuda, Koyo

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Article abstract of DOI:10.1246/cl.1983.1131

Thermally stable trimethylsilylmethyl azide was first synthesized from the reaction of chloromethyltrimethylsilane with sodium azide.Its use as an α-functionalized synthetic equivalent of methyl azide was demonstrated in the reaction with acetylenic dipol

Full text of DOI:10.1246/cl.1983.1131

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