A SILYL-FUNCTIONALIZED ALKYL AZIDE, TRIMETHYLSILYLMETHYL AZIDE; SYNTHESIS AND CYCLOADDITION REACTION TO ACETYLENIC DIPOLAROPHILES

DOI: 10.1246/cl.1983.1131

Source and publish data:

Chemistry Letters p. 1131 - 1134 (1983)

Update date:2022-08-05

Topics:

Authors:

Tsuge, Otohiko

Kanemasa, Shuji

Matsuda, Koyo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1983.1131

Thermally stable trimethylsilylmethyl azide was first synthesized from the reaction of chloromethyltrimethylsilane with sodium azide.Its use as an α-functionalized synthetic equivalent of methyl azide was demonstrated in the reaction with acetylenic dipol

Full text of DOI:10.1246/cl.1983.1131

Products guided by the article

Product name:(5-Benzoyl-3-trimethylsilanylmethyl-3H-[1,2,3]triazol-4-yl)-phenyl-methanone

Cas No:87576-90-7

R&D Labs maybe for 87576-90-7

Wuxi Forest Biological Co.,Ltd

Contact:+86-510-81602300

Address:Room 317,Building D, No.159 middle Chengjiang Road,Jiangyin Wuxi city.
JIANGXI XINXIN CHEMICAL CO., LTD.

Contact:86-15957176628

Address:INDUSTRY ROAD 1, INDUSTRIAL PARK, HEKOU TOWN,YANSHAN COUNTY, JIANGXI PROVINCE, CHINA
Changzhou Hopschain Chemical Co.,Ltd

website:http://www.hopschem.cn/products.html

Contact:86-519-85528066

Address:Room 710, Unit A, Xingbei Development Mansion, Tongjiang Road, Changzhou City,213000, China
Zhejiang Kaili Industrial Co., Ltd

Contact:+86-571-85241926

Address:lantian business center,No.18 Moganshan Road
Shanghai Bojing Chemical Co., Ltd.

Contact:021-37122233

Address:6F Buildiing 11,No.388,Baifu Road,District Fengxian.Shanghai, China.

Relevant to this article

Copper catalysed Gomberg-Bachmann-Hey reactions of arenediazonium tetrafluoroborates and heteroarenediazonium o-benzenedisulfonimides. Synthetic and mechanistic aspects

Doi:10.1016/j.tet.2020.131632
(2020)
Studies on reactivity of azidoamides, intermediates in the synthesis of tetrahydroxypipecolic acid derivatives

Doi:10.1016/j.tetasy.2008.03.018
(2008)
Synthesis of Cp′Ru(CO)(L)(η²-olefin)⁺ complexes and kinetic studies of Olefin substitution

Doi:10.1021/om061096u
(2007)
Phenylazoindole dyes - Part I: The syntheses, characterizations, crystal structures, quantum chemical calculations and antimicrobial properties

Doi:10.1016/j.saa.2013.04.081
(2013)
Copper incorporated nanorod like mesoporous silica for one pot aerobic oxidative synthesis of pyridines

Doi:10.1016/j.catcom.2014.09.003
(2015)
Efficient and selective alcoholysis of furfuryl alcohol to alkyl levulinates catalyzed by double SO₃H-functionalized ionic liquids

Doi:10.1039/c3gc41693c
(2014)

Article Doi