Electrocyclic Ring Opening of a β-Lithiocyclopropyloxirane. Generation and Trapping of (2Z,4E)-Cyclohepta-2,4-dienol

DOI: 10.1021/ja00363a020

Source and publish data:

Journal of the American Chemical Society p. 7322 - 7326 (1983)

Update date:2022-07-29

Topics:

Authors:

Coates, Robert M.

Last, Larry A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00363a020

A novel electrocyclic ring opening of a β-lithiocyclopropyloxirane is described.Metalation of exo-7-bromobicyclo<4.1.0>hept-2-ene anti-oxide (3) with n-butyllitium at 0 deg C afforded exo-bicyclo<3.2.0>hept-6-en-2-ol (4).A mechanism involving conrotatory

Full text of DOI:10.1021/ja00363a020

Products guided by the article

Product name:2-Cyclohepten-1-ol, 4,5-dibutyl-

Cas No:87598-40-1

R&D Labs maybe for 87598-40-1

DALIAN LICHUANG TRADE LTD

Contact:+8618032690252

Address:liaoning
Zhengzhou Minzhong Pharmaceutical Co.,ltd

Contact:0086-371-65797115

Address:15/F,Jiangshan Bldg, NO.126 Huanghe Road,Zhengzhou, China
Nanjing Y Bio-pharmaceutical Inc.

Contact:0518-85211163

Address:Building B, Dingyebaitai Mansion 10 Xinhuo Road Gaoxin District , Nanjing city, Jingsu Province China
Yantai Jiacheng Chemical Technology Co., Ltd.

Contact:535-6303697,18663837927

Address:70# Qunying Road, Fushan District,Yantai, China
Jewim Pharmaceutical (Shandong) Co., Ltd

Contact:+8615621883869

Address:山东省泰安市高新技术产业开发区配天门大街西首

Relevant to this article

Open saccharin-based secondary sulfonamides as potent and selective inhibitors of cancer-related carbonic anhydrase IX and XII isoforms

Doi:10.1080/14756366.2016.1235040
(2016)
Enantioselective aza-Henry reactions assisted by Zn^II and N-methylephedrine

Doi:10.1002/anie.200502674
(2006)
Synthesis, coordination chemistry, and metal complex reactivity of (dimethylamino)methyl-substituted triarylphosphanes; X-ray study on [AuCl(PPh_{3 - N}Ar_n)] (Ar = 1-C₆H ₃(CH₂NMe₂)₂

Doi:10.1016/j.jorganchem.2005.09.009
(2006)
Synthesis of the tricyclic core of solanoeclepin A through intramolecular [2+2] photocycloaddition of an allene butenolide

Doi:10.1002/ejoc.200500609
(2006)
A facile three-component one-pot synthesis of structurally constrained tetrahydrofurans that are t-RNA synthetase inhibitor analogues

Doi:10.1021/jo0497508
(2004)
Spectroscopic and crystallographic investigations of novel Bodipy-derived metal-organic frameworks

Doi:10.1021/ic502219y
(2015)

Article Doi