Journal of the American Chemical Society p. 7322 - 7326 (1983)
Update date:2022-07-29
Topics:
Coates, Robert M.
Last, Larry A.
A novel electrocyclic ring opening of a β-lithiocyclopropyloxirane is described.Metalation of exo-7-bromobicyclo<4.1.0>hept-2-ene anti-oxide (3) with n-butyllitium at 0 deg C afforded exo-bicyclo<3.2.0>hept-6-en-2-ol (4).A mechanism involving conrotatory
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