Journal of Organometallic Chemistry p. C17 - C21 (1986)
Update date:2022-08-04
Topics:
Heinicke, J.
Nietzschmann, E.
Tzschach, A.
Phosphinous acid o-bromoaryl esters or phosphorous acid o-haloaryl ester diamides react with sodium under mild conditions to give the corresponding sodium aryls which undergo rapid 1,3-carbanionic rearrangements to give o-phosphinophenolates.These may be worked up to the free phenoles or silylated by treatment with Me3SiCl.
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