Journal of Organic Chemistry p. 74 - 78 (1984)
Update date:2022-09-26
Topics:
Yokoyama, Masataka
Kodera, Masahito
Imamoto, Tsuneo
The mechanism of the "S,N double rearrangement" was studied by 13C labeling and crossover reactions.The results indicate that the condensation is a thiallylic rearrangement of the initial ring-closure product formed from the cyano and mercapto groups of the starting compound and benzoic acid.
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Doi:10.1021/ja01141a022
()Doi:10.1021/ja057908f
(2006)Doi:10.1021/jo00196a022
(1984)Doi:10.1016/j.bmcl.2005.03.057
(2005)Doi:10.1038/s41557-018-0065-0
(2018)Doi:10.1016/0009-2614(83)87019-5
(1983)
