TRANSPOSITION DE L'ATOME D'AZOTE DE DIALKYLAMINOPENTOPYRANOSIDES; MISE EN EVIDENCE DE SELS D'AZIRIDINIUM INTERMEDIAIRES

DOI: 10.1016/S0040-4020(01)88690-7

Source and publish data:

Tetrahedron p. 1797 - 1802 (1983)

Update date:2022-08-05

Topics:

Authors:

Picq, D.

Cottin, M.

Anker, D.

Pacheco, H.

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Article abstract of DOI:10.1016/S0040-4020(01)88690-7

Methyl pyranosides with dimethylamino and sulfonyloxy groups in trans relationship undergo rearrangement with participation of the dimethylamino group.This rearrangement results in a 1,2-shift of the nitrogen function which is assumed to be concerted in a

Full text of DOI:10.1016/S0040-4020(01)88690-7

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