Bond Fixation in Annulenes. 15. A Titanium(0)-Mediated Synthesis of a Cyclooctatetraene. Probe of the Relative Size of the Interstitial Phenyl Substituent in 1,3-Dimethyl-2-phenylcyclooctatetraene by means of Racemization Kinetics

DOI: 10.1021/ja00364a030

Source and publish data:

Journal of the American Chemical Society p. 7644 - 7648 (1983)

Update date:2022-08-04

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Authors:

Paquette, Leo A.

Gardlik, John M.

McCullough, Kevin J.

Hanzawa, Yuji

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Article abstract of DOI:10.1021/ja00364a030

A fully regiospecific synthesis of racemic 1,3-dimethyl-2-phenylcyclooctatetraene (23a) has been achieved on the basis of the expectation that trans-4-methyl-5-acetyl-4-cyclohexenyl phenyl ketone (21a) would undergo efficient titanium(0)-promoted cyclizat

Full text of DOI:10.1021/ja00364a030

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