Bond Fixation in Annulenes. 15. A Titanium(0)-Mediated Synthesis of a Cyclooctatetraene. Probe of the Relative Size of the Interstitial Phenyl Substituent in 1,3-Dimethyl-2-phenylcyclooctatetraene by means of Racemization Kinetics

DOI: 10.1021/ja00364a030

Source and publish data:

Journal of the American Chemical Society p. 7644 - 7648 (1983)

Update date:2022-08-04

Topics:

Authors:

Paquette, Leo A.

Gardlik, John M.

McCullough, Kevin J.

Hanzawa, Yuji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00364a030

A fully regiospecific synthesis of racemic 1,3-dimethyl-2-phenylcyclooctatetraene (23a) has been achieved on the basis of the expectation that trans-4-methyl-5-acetyl-4-cyclohexenyl phenyl ketone (21a) would undergo efficient titanium(0)-promoted cyclizat

Full text of DOI:10.1021/ja00364a030

Products guided by the article

Product name:C₁₀H₁₁⁽²⁾H₃O₃

Cas No:87923-16-8

R&D Labs maybe for 87923-16-8

Zibo Linzi Darong Fine Chemical Co., Ltd(expird)

Contact:86-532-67773200; 15689126900

Address:Qidu town,Linzi district,Zibo city,Shandong province,China
Nantong Baokai Chemical Co., Ltd (Hangzhou Baokai Bio-Chemicals Co.,Ltd.)

Contact:+86-513-83886111

Address:No. 68 Suzhou road ,Binjiang Fine Chemical Industrial Park , Beixin town, Qidong city ,Jiangsu province
Changzhou naidechemical Co.Ltd

Contact:+86-519-82589807

Address:NO.25,Houyang street,Jintan,Changzhou City
Shanghai ZaiQi Bio-Tech Co., Ltd.,

Contact:+86-21-5482 4098

Address:Bldg. No.7, No.201 MinYi Rd，Songjiang CaoHeJing High-Tech Park Shanghai 201516 P,R,China
Watson International Ltd

Contact:+44 (0)2036089360-31

Address:Chanceryhouse,Chancery Lan

Relevant to this article

THE SYNTHESIS OF FUSED AND BRIDGED RING SYSTEMS BY FREE RADICAL CARBOCYCLIZATION. A GENERAL ROUTE TO MASKED 1,4-DIKETONES.

Doi:10.1016/S0040-4039(00)81793-1
(1983)
t-BUTOXYMETHYLLITHIUM: DIRECT PREPARATION FOM t-BUTYL METHYL ETHER AND APPLICATIONS AS A HYDROXYMETHYL ANION EQUIVALENT

Doi:10.1016/S0040-4039(00)88125-3
(1983)
Syntheses of O⁶-alkyl- and arylguanine derivatives: Nucleobase adducts derived from styrene 7,8- and 3,4-oxides

Doi:10.1002/ejoc.200500477
(2006)
Mononuclear metal phosphinates with ancillary pyrazole ligands. Synthesis and X-ray crystal structures of [M(Ph₂PO₂) ₂(3,5-DMPZ)₂] (M = Co, Zn)

Doi:10.1002/zaac.200500118
(2005)
THE ALKYLATION AND BASE-PROMOTED RING-OPENING REACTION OF 3-PHENYLSULFONYL-3-TRIMETHYLSILYLCYCLOBUTANOLS. A NEW METHOD FOR THE PREPARATION OF β-METHYLENE KETONES

Doi:10.1246/cl.1983.1285
(1983)
Iron-catalyzed inexpensive and practical synthesis of N-substituted pyrroles in water

Doi:10.1055/s-0029-1217799
(2009)

Article Doi