MECHANISM OF THE REACTION OF TRIALKYLBORANES WITH α-AZIDOSTYRENE

DOI: 10.1016/S0040-4039(00)94533-7

Source and publish data:

Tetrahedron Letters p. 3779 - 3782 (1983)

Update date:2022-09-26

Topics:

Authors:

Bamford, Anthony F.

Cook, Malcolm D.

Roberts, Brian P.

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Article abstract of DOI:10.1016/S0040-4039(00)94533-7

Trialkylboranes and α-azidostyrene react, with evolution of nitrogen, to give iminoboranes R₂BN=C(CH₂R)Ph by free radical chain mechanism involving intermediate α-azidoalkyl and iminyl radicals.

Full text of DOI:10.1016/S0040-4039(00)94533-7

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