Journal of Organometallic Chemistry p. 55 - 68 (1994)
Update date:2022-08-03
Topics:
Corriu, Robert
Lanneau, Gerard
Priou, Christian
Soulairol, Florence
Auner, Norbert
et al.
Generation by two different methods of silylenes stabilized by o-amino(aryl) groups is reported.The halodemetallation of difluoro- or dichloro-silanes with Li metal or lithium-naphthalene gave the same product, a stabilized sila-ylide (hypercoordinated silylene).Intramolecular Lewis base stabilization is not sufficient to isolate a monomeric species.The silylenes, however, have been trapped with 2,3-dimethylbutadiene.An unexpected intramolecular rearrangement to silaacenaphthene has been observed in the case of a six-membered ring amino(aryl) coordinated silylene.Photolysis of o-1-<(N,N-dimethylamino)methyl>-2-
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