A NEW ROUTE FOR FORMATION OF THE CARBON-PHOSPHORUS BOND, AND SYNTHESIS OF 1,2,4-TRI-O-ACETYL-5-DEOXY-3-O-METHYL-5-C--α- AND -β-D-XYLOPYRANOSE

Article abstract of DOI:10.1016/0008-6215(83)84049-X

Deoxygenation at the carbon atom α to the phosphorus atom of 1,2-O-isopropylidene-5-C-(methoxyphenylphosphinyl)-3-O-methyl-α-D-xylofuranose (7), prepared from 1,2-isopropylidene-3-O-methyl-α-D-xylo-pentodialdo-1,4-furanose by reaction with methyl phenylph