Configurational Stability of the 2,2-Diphenyl-1-(trimethylsilyl)cyclopropyl Carbanion and Free Radical. Absolute Stereochemical Assigments to Select Silylcyclopropanes.

DOI: 10.1021/ja00314a014

Source and publish data:

Journal of the American Chemical Society p. 335 - 340 (1984)

Update date:2022-09-26

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Authors:

Paquette, Leo A.

Uchida, Takane

Gallucci, Judith C.

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Article abstract of DOI:10.1021/ja00314a014

2,2-Diphenylcyclopropanecarboxylic acid was silylated at the 1-position and this product was resolved l-cinchonidine.The resulting optically active acid was transformed into (-)-2,2-diphenyl-1-methyl-1-(trimethylsilyl)cyclopropane, whose absolute configur

Full text of DOI:10.1021/ja00314a014

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