Journal of Organic Chemistry p. 5409 - 5411 (1983)
Update date:2022-07-30
Topics:
Molander, Gary A.
Allylzinc bromide (1) reacts with a variety of 1-(trimethylsilyl)-1-alkynes to provide regio- and stereoselective carbometalated products 3, the zinc atom being placed at the carbon bearing the silicon.Under the conditions of the reaction, the stereochemistry of the products is highly dependent on the structure of 2.
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Doi:10.1246/cl.1984.127
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