Kinetics and Mechanism of Nucleophilic Displacements with Heterocycles as Leaving Groups. Part 9. N-Substituted 2,4,6-Triphenylpyridiniums, 5,6-Dihydro-2,4-diphenylbenzoquinoliniums, and 5,6,8,9-Tetrahydro-7-phenyldibenzoacridiniums: Kinetic Rate

DOI: 10.1039/P29830001427

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 1427 - 1434 (1983)

Update date:2022-08-05

Topics:

Authors:

Katritzky, Alan R.

Sakizadeh, Kumars

Ou, Yu Xiang

Jovanovic, Bratislav

Musumarra, Giuseppe

et al. et al.

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Article abstract of DOI:10.1039/P29830001427

N-n-Alkyl, N-s-alkyl, N-allyl, and N-benzyl derivatives of the title compounds react with piperidine and other nucleophiles in clearly separable S_N1 and/or S_N2 reactions.For N-s-alkyl compounds, S_N2 rates decrease with nuc

Full text of DOI:10.1039/P29830001427

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