ASYMMETRISCHE INDUKTION BEI DER NICKEL(0)-KATALYSIERTEN -CYCLOADDITION VON METHYLENCYCLOPROPAN MIT CHIRALEN ALKYLACRYLATEN

DOI: 10.1016/S0040-4039(00)88178-2

Source and publish data:

Tetrahedron Letters p. 3599 - 3602 (1983)

Update date:2022-08-03

Topics:

Authors:

Binger, Paul

Brinkmann, Axel

Richter, Wolf Juergen

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Article abstract of DOI:10.1016/S0040-4039(00)88178-2

Starting from enantiomerically pure alkylacryletes Nickel(0)-catalyzed <3+2> cycloaddition with methylenecyclopropane can be achieved giving 3-methylenecyclopentanecarboxylic acid alkylesters in high yields with 3 to 64percent asymmetric induction.

Full text of DOI:10.1016/S0040-4039(00)88178-2

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