Conversion of Tetrahydroisoquinolinium Salts into Benzazepines

DOI: 10.1021/jo00178a001

Source and publish data:

Journal of Organic Chemistry p. 581 - 586 (1984)

Update date:2022-08-04

Topics:

Authors:

Smith, Stephen

Elango, Varadaraj

Shamma, Maurice

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00178a001

Rearrangement of tetrahydroisoquinolinium salt 3 upon treatment with potassium tert-butoxide in tert-butyl alcohol gives benzazepine 5.Similar treatment of salt 11 yields mostly cis benzazepine 13 together with a little trans 14.In like fashion, a mixture

Full text of DOI:10.1021/jo00178a001

Products guided by the article

Product name:trans-6-Hydroxy-7-methoxy-N-methyl-N-(p-nitrobenzyl)-1-phenyl-1,2,3,4-tetrahydroisoquinolinium Bromide

Cas No:88156-86-9

R&D Labs maybe for 88156-86-9

Ningbo Distant Chemicals Co.,Ltd

Contact:86-574-27862490,27862438

Address:5F-3,#54 DaShaNi street,Ningbo,CHINA
Xinchang Yueding Chemical Co., Ltd.

Contact:86-571-56926323

Address:NO.90 BEIMENCHENGWAI CHENGGUAN TOWN XINCHANG
Zhejiang Genebest Pharmaceutical Co.,Ltd.

Contact:0086-571-63532866

Address:No.1 Jinboshi Rd Lishan Town Fuyang City Zhejiang Province China
Jiangsu Cale New Material Co.ltd

Contact:+86-515-88334667/88203550

Address:Zhongshan 3rd Road, Coastal Chemical Industry Park, Yancheng, Jiangsu, China
Chengdu CSH Pharmaceutical Co.,ltd

Contact:+86-(28)-85321971

Address:Block B,New Hope Int. Tian Fu New District, Chengdu, Sichuan, China

Relevant to this article

Hydrothermal synthesis, structure, and magnetic properties of a three-dimensional polymeric Ni^II complex, [Ni(bpp)(NIP)(H ₂O)]_n (bpp = 1,3-di(4-pyridyl)propane, NIP = 5-nitroisophthalate)

Doi:10.1002/zaac.200500199
(2005)
General and mild preparation of 2-aminopyridines

Doi:10.1021/ol102301u
(2010)
Synthesis and SAR of piperazinyl-N-phenylbenzamides as inhibitors of hepatitis C virus RNA replication in cell culture

Doi:10.1016/j.bmcl.2009.01.066
(2009)
A series of spirocyclic analogues as potent inhibitors of bacterial phenylalanyl-tRNA synthetases

Doi:10.1016/j.bmcl.2003.11.081
(2004)
Iron-catalyzed cross-coupling between alkenyl and dienyl sulfonates and functionalized arylcopper reagents

Doi:10.1055/s-2006-932451
(2006)
Doi:10.1021/ja00520a015
(1979)

Article Doi