Conversion of Tetrahydroisoquinolinium Salts into Benzazepines

DOI: 10.1021/jo00178a001

Source and publish data:

Journal of Organic Chemistry p. 581 - 586 (1984)

Update date:2022-08-04

Topics:

Authors:

Smith, Stephen

Elango, Varadaraj

Shamma, Maurice

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Article abstract of DOI:10.1021/jo00178a001

Rearrangement of tetrahydroisoquinolinium salt 3 upon treatment with potassium tert-butoxide in tert-butyl alcohol gives benzazepine 5.Similar treatment of salt 11 yields mostly cis benzazepine 13 together with a little trans 14.In like fashion, a mixture

Full text of DOI:10.1021/jo00178a001

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Product name:trans-6-Hydroxy-7-methoxy-N-methyl-N-(p-nitrobenzyl)-1-phenyl-1,2,3,4-tetrahydroisoquinolinium Bromide

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