Synthesis, Structural Characterization, and Electronic Structures of the "Mixed" Terminal Ligand Cubanes 2- (X=S, O) and 2-. The First Examples of 2+ Cores with a Nonco

Article abstract of DOI:10.1021/ja00328a033

Mixed terminal ligand iron-sulfur clusters of the type (Ph4P)2 (L=SPh, L'=Cl, OPh, Br; L=OPh, L'=Cl) have been synthesized in good yields by the reaction of ^2- (X=Cl, Br) with 2 equiv of KSPh or NaOPh and by the reactio