Chemistry Letters p. 1525 - 1528 (1983)
Update date:2022-07-30
Topics:
Tsuge, Otohiko
Wada, Eiji
Kanemasa, Shuji
The stereoselectivity of diene-transmissive Diels-Alder reaction of a cross-conjugated triene, 3-benzylidene-2,4-bis(trimethylsilyloxy)-1,4-pentadiene, with a variety of olefinic dienophiles was investigated.Cyclic dienophiles gave the stereoselective bis-adducts via the endo mono-cycloadducts, whereas the exo mono-adducts were obtained as major products in the reaction with acyclic dienophiles.The steric regulation of diene-transmissive Diels-Alder reaction was discussed.
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Doi:10.1246/bcsj.35.510
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(1983)
