SYNTHESIS OF SCILLASCILLIN, A NATURALY OCCURRING BENZOCYCLOBUTANE

DOI: 10.1016/S0040-4039(00)94146-7

Source and publish data:

Tetrahedron Letters p. 5581 - 5584 (1983)

Update date:2022-08-02

Topics:

Authors:

Rawal, Viresh H.

Cava, Michael P.

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Article abstract of DOI:10.1016/S0040-4039(00)94146-7

The novel homoisoflavanone scillascillin has been synthesized from phloroglucinol.The sequence described represents the first synthesis of a naturally occurring benzocyclobutane.The first example of a silyl transfer involving an 8-membered transition state is reported.

Full text of DOI:10.1016/S0040-4039(00)94146-7

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