CARBON-CARBON BOND FORMATION WITH BISMUTH SALT. A CHEMOSELECTIVE GRIGNARD-TYPE ADDITION OF ALLYL UNIT TO ALDEHYDES

DOI: 10.1016/S0040-4039(00)85061-3

Source and publish data:

Tetrahedron Letters p. 4771 - 4774 (1986)

Update date:2022-08-05

Topics:

Authors:

Wada, Makoto

Ohki, Hidenori

Akiba, Kin-ya

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Article abstract of DOI:10.1016/S0040-4039(00)85061-3

In the presence of bismuth(III) chloride-metallic zinc or bismuth(III) chloride-metallic iron, allylic halides were found to react with aldehydes under mild conditions to give the corresponding homoallylic alcohols in high yields with high chemoselectivity.

Full text of DOI:10.1016/S0040-4039(00)85061-3

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