HIGHLY STEREOSELECTIVE AXIAL ADDITION OF ETHYNYL CARBANIONS TO THE CARBONYL OF CYCLOHEXANONES

DOI: 10.1016/S0040-4039(01)99802-8

Source and publish data:

Tetrahedron Letters p. 4887 - 4890 (1983)

Update date:2022-08-03

Topics:

Authors:

Stork, Gilbert

Stryker, Jeffrey

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Article abstract of DOI:10.1016/S0040-4039(01)99802-8

This communication reports that highly stereoselective axial addition of ethynyl anions is the normal result with conformationally defined conjugated cyclohexanones, in the absence of overriding steric factors.

Full text of DOI:10.1016/S0040-4039(01)99802-8

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