Activation Parameters for Intramolecular Nucleophilic Substitution by Carbanions - the Insignificant Effect of Ring Strain on Cylisation Rates

DOI: 10.1039/c39830001374

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1374 - 1376 (1983)

Update date:2022-08-04

Topics:

Authors:

Benedetti, Fabio

Stirling, Charles J. M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39830001374

Activation parameters for the cyclisation of bis-sulphonyl-stabilised carbanions to bis-sulphonylcycloalkanes have been determined; cyclopropanes form nearly a million-fold faster than cyclobutanes and ring strain is a negligible factor in determining rea

Full text of DOI:10.1039/c39830001374

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Benzene, 1,1'-[(4-chlorobutylidene)bis(thio)]bis-

Cas No:89593-91-9

R&D Labs maybe for 89593-91-9

Zhejiang Haizhou Pharmaceutical Co., Ltd.

website:https://www.haizhoupharma.com/

Contact:+86-576-88221016

Address:No. 19, Donghai 5th Avenue, Yanhai Industrial Zone, Linhai, Zhejiang, China
WUHAN WELLSONG INT'L CO.,LTD

Contact:+86-27-85733560

Address:NO.308,QINGNIAN RD.,WUHAN,CHINA
JenKem Technology Co., Ltd.

Contact:86-10-62983737; +86-10-51287608

Address:4/F Building C, 2 Shangdi Xinxi Road
Ningbo Distant Chemicals Co.,Ltd

Contact:86-574-27862490,27862438

Address:5F-3,#54 DaShaNi street,Ningbo,CHINA
Lonzeal Pharmaceuticals Co., Ltd.

website:http://www.lonzeal.com

Contact:+86-13381011962

Address:RM 801, Yue MOMA, No. 26 Anningzhuang Rd. Haidian District, Beijing, China

Relevant to this article

Structure of oxazolomycin, a novel β-lactone antibiotic

Doi:10.1016/S0040-4039(00)98515-0
(1985)
Amination of 1,3-dihalo-2-nitrosobenzenes

Doi:10.1134/S1070428006090065
(2006)
RHODIUM(II) ACETATE-CATALYZED REACTION OF ETHYL 2-DIAZO-3-OXOPENT-4-ENOATES: SIMPLE ROUTES TO 4-ARYL-2-HYDROXY-1-NAPHTHOATES AND β,γ-UNSATURATED ESTERS. THE DIANION OF ETHYL 4-(DIETHYLPHOSPHONO)ACETOACETATE AS A PROPIONATE EQUIVALENT

Doi:10.1016/S0040-4039(00)94110-8
(1983)
THE RELATIVE STEREOCHEMISTRY OF SOME α-METHYL-β-SILYLCARBONYL COMPOUNDS PRODUCED BY THE DIASTEREOSELECTIVE ALKYLATION OF β-SILYLENOLATES

Doi:10.1016/0022-328X(84)85181-5
(1984)
Highly stereocontrolled synthesis of carbacyclin from acyclic starting materials via Ti(II)-Mediated tandem cyclization [10]

Doi:10.1021/ja002974x
(2000)
Doi:10.1021/ja00870a021
(1962)

Article Doi