Activation Parameters for Intramolecular Nucleophilic Substitution by Carbanions - the Insignificant Effect of Ring Strain on Cylisation Rates

DOI: 10.1039/c39830001374

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1374 - 1376 (1983)

Update date:2022-08-04

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Authors:

Benedetti, Fabio

Stirling, Charles J. M.

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Article abstract of DOI:10.1039/c39830001374

Activation parameters for the cyclisation of bis-sulphonyl-stabilised carbanions to bis-sulphonylcycloalkanes have been determined; cyclopropanes form nearly a million-fold faster than cyclobutanes and ring strain is a negligible factor in determining rea

Full text of DOI:10.1039/c39830001374

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