Direct catalytic asymmetric Mannich-type reactions of isomerizable aliphatic imines: chemoselective enolate formation from a hydroxyketone by a Zn-catalyst

DOI: 10.1016/j.tetlet.2006.04.016

Source and publish data:

Tetrahedron Letters p. 3985 - 3989 (2006)

Update date:2022-08-04

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Authors:

Yamaguchi, Akitake

Matsunaga, Shigeki

Shibasaki, Masakatsu

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Article abstract of DOI:10.1016/j.tetlet.2006.04.016

A direct catalytic asymmetric Mannich-type reaction of isomerizable aliphatic imines is described. A Et₂Zn/(S,S)-linked-BINOL complex was suitable for chemoselective enolate formation from a hydroxyketone in the presence of isomerizable aliphat

Full text of DOI:10.1016/j.tetlet.2006.04.016

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