Reductive elimination of dimethylcarbonate from (dimethoxycarbonyl)tricarbonyl cobaltates. Isolation and crystal structures of Cs and K

Article abstract of DOI:10.1016/0022-328X(91)80188-P

Salts of the anion ^- with Cs⁺ and K⁺ (with the latter cation complexed by dibenzo-18-crown-6 ether) have been isolated and structurally characterized.In the trigonal bipyramidal cobaltate two C-coordinate