Organometallics p. 1104 - 1107 (1984)
Update date:2022-08-04
Topics:
Shreeve, Jean'ne M.
Williamson, Stanley M.
The reactions of P(OCH2CF3)3 with three different types of metallocarbonyl compounds Ni(CO)4, (η5-C5H5)Fe(CO)2I, and (η6-1,3,5-(CH3)3C6H 3)Cr(CO)3 cleanly form products derived from displacement of CO. The products (CO)Ni(P(OCH2CF3)3)3, (CO)2Ni(P(OCH2CF3)3)2, (η5-C5H5)FeI(P(OCH2CF 3)3)2, and (η6-1,3,5-(CH3)3C6H 3)Cr(CO)2P(OCH2CF3)3 are obtained in good yields and are relatively stable. Both thermal and photochemical modes of reaction are observed.
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