Highly selective synthesis of 4-vinylcyclohexene by cyclodimerization of butadiene catalysed by aminophosphinephosphinite and bis(aminophosphine) chiral ligands nickel complexes

DOI: 10.1016/0040-4039(94)85067-4

Source and publish data:

Tetrahedron Letters p. 413 - 416 (1994)

Update date:2022-08-03

Topics: Nickel complexes Butadiene Cyclodimerization

Authors:

Suisse, Isabelle

Bricout, Herve

Mortreux, Andre

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Article abstract of DOI:10.1016/0040-4039(94)85067-4

The highest chemoselective synthesis of 4-vinylcyclohexene ever observed by butadiene cyclodimerization on nickel complexes has been obtained with aminophosphinephosphinite and bis(aminophosphine) chiral ligands (selectivity up to 99%).

Full text of DOI:10.1016/0040-4039(94)85067-4

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